SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC -- 1508 SEMI-GLOSS WHITE DECORATOR PAINTS -- -
===================== Product Identification ===================== Product ID:1508 SEMI-GLOSS WHITE DECORATOR PAINTS MSDS Date:12/01/1996 FSC:NIIN:Submitter:D DG Status Code:A MSDS Number: CKVNT === Responsible Party === Company Name:SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC Address:31500 SOLON ROAD City:SOLON State:OH ZIP:44139 Country:US Info Phone Num:800-247-3270; 800-832-2541 Emergency Phone Num:216-566-2917 Resp. Party Other MSDS Num.:DEC/KR-1 CAGE:TO019 === Contractor Identification === Company Name:SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC Address:31500 SOLON ROAD Box:City:SOLON State:OH ZIP:44139 Country:US Phone:800-247-3270; 216-566-2917 CAGE:TO019 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 = Wt:14. OSHA PEL:1800 MG/M3;1000 PPM Ingred Name:BUTANE CAS:106-97-8 RTECS #:EJ4200000 = Wt:6. ACGIH TLV:1900 MG/M3;800 PPM Ingred Name:ACETONE CAS:67-64-1 RTECS #:AL3150000 = Wt:37. OSHA PEL:2400 MG/M3;1000 PPM ACGIH TLV:1780 MG/M3;750 PPM ACGIH STEL:2380 MG/M3;1000 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYLBENZENE CAS:100-41-4 RTECS #:DA0700000 = Wt:2. OSHA PEL:435 MG/M3;100 PPM ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:543 MG/M3;125 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE CAS:1330-20-7 RTECS #:ZE2100000 = Wt:10. ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:651 MG/M3;150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:1-BUTANOL CAS:71-36-3 RTECS #:EO1400000 = Wt:1. OSHA PEL:300 MG/M3;100 PPM ACGIH STEL:C152 MG/M3;C50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL METHYL KETONE CAS:78-93-3 RTECS #:EL6475000 = Wt:4. OSHA PEL:590 MG/M3;200 PPM ACGIH TLV:590 MG/M3;200 PPM ACGIH STEL:885 MG/M3;300 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:1-METHOXY-2-PROPANOL ACETATE CAS:108-65-6 RTECS #:AI8925000 = Wt:.5 Ingred Name:BARIUM SULFATE CAS:7727-43-7 RTECS #:CR0600000 = Wt:2. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 = Wt:7. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:IRRITATION OF EYES, SKIN AND RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS AND POSSIBLY DEATH. CHRONIC: PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS MAY CAUSE ADVERSE EFFECTS TO LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR & REPRODUCTIVE SYSTEMS. METHYL ETHYL KRTONE MAY INCREASE THE NERVOUS SYSTEM EFFECTS OF OTHER SOLVENTS. METHYL ETH YL KETONE MAY INCREASE THE NERVOUS SYSTEM EFFECTS OF OTHER SOLVENTS. REPORTS HAVE ASSOCIATED REPEATED OR PROLONGED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. Explanation of Carcinogenicity:NO INGREDIENT IN THESE PRODUCTS IS AN IARC, NTP OR OSHA LISTED CARCINOGEN. Effects of Overexposure:HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS. TENDERNESS AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXP OSURE. Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:IF INHALED: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. IF ON SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE USE. IF IN EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. IF SWALLOWED: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. GIVE CONSCIOUS PA TIENT SEVERAL GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:<-17.6C, 0.F Lower Limits:1.0 Upper Limits:13.1 Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CO NTAINERS TO PREVENT PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS & OPEN FLAME. APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRE CAUTIONS. DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME. VAPORS WILL ACCUMULATE READILY & MAY IGNITE EXPLOSIVELY. DURING USE & UNTIL ALL VAPORS ARE GONE. KEEP AREA VENTILATED-DO NOT SMOKE-EXTINGUISH ALL FLAMES, PILO T LIGHTS & HEATERS -TURN OFF STOVES, ELECTRIC TOOLS & APPLIANCES, ANY OTHER SOURCES OF IGNITION. Other Precautions:CONSULT NFPA CODE. USE APPROVED BONDING & GROUNDING PROCEDURES. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE, OR EXPOSE TO TEMPERATURE ABOVE 120F. HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT WA TER, & OTHER HEAT SOURCES COULD CAUSE CONTAINERS TO BURST. DO NOT TAKE INTERNALLY. KEEP OUT OF THE R EACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST INGREDIENTS. WHEN SANDING OR ABRADING THE DRIED FILM, WEAR A DUST/MIST RESPIRATOR APPROVED BY NIOSH/MSHA FOR DUST WHICH MAY BE GENERATED FROM THIS PRODUCT. Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE EXPOSURE TO MATERIALS IN SECTION II IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS. Protective Gloves:NONE REQUIRED FOR NORMAL APPLICATION OF AEROSOL PRODUCTS . Eye Protection:SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS. Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. Supplemental Safety and Health INTENTIONAL MISUSE OF DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL OR FATAL. ================== Physical/Chemical Properties ================== HCC:V3 Boiling Pt:B.P. Text:<0 - 302F Vapor Density:>AIR VOC Grams/Liter:2.9 Evaporation Rate & Reference:FASTER THAN ETHER Appearance and Odor:COLOR: WHITE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF METALS IN INGREDIENTS. =================== Toxicological Information =================== Toxicological Information:RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH PRESSURE ELEVELS ARE NOT ATTAINABLE IN THE WORKPLACE. . WEIGHT PER GALLONS (LBS.): 6.77. VOC AS A PERCENT BY WEI GHT PER BAAQMD & CARB: 43.4. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT INCINERATE. DEPRESSURIZE CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS REGARDING POLLUTION. ===================== Regulatory Information ===================== SARA Title III Information:ETHYLBENZENE, XYLENE, 1-BUTANOL, METHYL ETHYL KETONE & BARIUM COMPOUND (% BARIUM, 0[1[): INGREDIENTS SUBJECT TO THE REPORTING REQUIREMENTS OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) SE CTION 313, 40 CFR 372.65C. Federal Regulatory Information:TSCA CERTIFICATION: ALL CHEMICALS IN THESE PRODUCTS ARE LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA INVENTORY. State Regulatory Information:WARNING: THESE PRODUCTS CONTAIN A CHEMICAL/S KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.